https://ogma.newcastle.edu.au/vital/access/ /manager/Index en-au 5 https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:13193 2 (¹∆) whose formation is catalysed by the reactor surfaces, initiates the reaction at this low temperature. Quantum chemical computations of the reaction potential energy surfaces suggest low energy pathways to the observed initial products.]]> Wed 11 Apr 2018 13:51:15 AEST ]]> https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:46009 Wed 10 Apr 2024 15:33:13 AEST ]]> https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:996 Sat 24 Mar 2018 08:29:49 AEDT ]]> https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:28926 600°C). The low temperature phenomena have been studied by quantum chemical techniques and reaction mechanisms to explain products’ formation (including the MCD 3-chlorodibenzofuran) are given. 3-Chlorodibenzofuran (the simplest PCDF) and benzaldehyde are important low temperature products produced by O2 (1∆) in reactors (1) and (2). Both O2 (1∆) and ground state O2 (3 Σ g) can displace Cl atoms from 4-chlorobiphenyl to produce polychlorobenzenes although only O2 (1Δ) produces significant yields of chlorobenzenes at low temperatures. Styrene and naphthalene also arise from O2 displacement of Cl.]]> Sat 24 Mar 2018 07:31:26 AEDT ]]> https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:30034 Sat 24 Mar 2018 07:24:20 AEDT ]]> https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:23116 Sat 24 Mar 2018 07:15:30 AEDT ]]>